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Model for reversible colloidal gelation.
- Source :
-
Physical review letters [Phys Rev Lett] 2005 Jun 03; Vol. 94 (21), pp. 218301. Date of Electronic Publication: 2005 Jun 02. - Publication Year :
- 2005
-
Abstract
- We report a numerical study, covering a wide range of packing fraction Phi and temperature T, for a system of particles interacting via a square well potential supplemented by an additional constraint on the maximum number n(max) of bonded interactions. We show that, when n(max)<6, the liquid-gas coexistence region shrinks, giving access to regions of low Phi where dynamics can be followed down to low T without an intervening phase separation. We characterize these arrested states at low densities (gel states) in terms of structure and dynamical slowing down, pointing out features which are very different from the standard glassy states observed at high Phi values.
- Subjects :
- Gels
Models, Theoretical
Temperature
Viscosity
Biophysics methods
Colloids chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 0031-9007
- Volume :
- 94
- Issue :
- 21
- Database :
- MEDLINE
- Journal :
- Physical review letters
- Publication Type :
- Academic Journal
- Accession number :
- 16090355
- Full Text :
- https://doi.org/10.1103/PhysRevLett.94.218301