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Substituent dependence of the reactions of [RuCl2(PPh3)3] with bulky aromatic thiols.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2006 Mar 14 (10), pp. 1267-70. Date of Electronic Publication: 2006 Jan 10. - Publication Year :
- 2006
-
Abstract
- 2,4,6-trialkylbenzenethiols react with [RuCl2(PPh3)3] to give Ru products with the alkyl substituents forming M-C sigma bonds, carbene, carbene with a S alpha-heteroatom, agostic hydrogen interaction or a simple tetrahedral Ru(II) species, depending on the substituent.
Details
- Language :
- English
- ISSN :
- 1477-9226
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 16505904
- Full Text :
- https://doi.org/10.1039/b515244e