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[Bis(trimethylsilyl)amido-kappaN]{tert-butyl[(E)-2-(tert-butylimino)ethyl]amido-kappa(2)N,N'}tin(II), a key intermediate in the synthesis of 1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazastannole.

Authors :
Guzei IA
Timokhin VI
West R
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2006 Mar; Vol. 62 (Pt 3), pp. m90-2. Date of Electronic Publication: 2006 Feb 11.
Publication Year :
2006

Abstract

The title compound, [Sn(C10H21N2)(C6H18NSi2)], contains the Sn(II) centre in a trigonal-pyramidal geometry. The basal plane is formed by three N atoms and the fourth apical position is occupied by a stereoactive lone pair. The Sn atom is displaced from the plane of the three N atoms by 1.1968 (12) A. The Sn-N bonds are highly polarized toward the N atoms, as confirmed by natural bonding orbital analysis.

Details

Language :
English
ISSN :
0108-2701
Volume :
62
Issue :
Pt 3
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
16518038
Full Text :
https://doi.org/10.1107/S0108270106001697