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[Bis(trimethylsilyl)amido-kappaN]{tert-butyl[(E)-2-(tert-butylimino)ethyl]amido-kappa(2)N,N'}tin(II), a key intermediate in the synthesis of 1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazastannole.
- Source :
-
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2006 Mar; Vol. 62 (Pt 3), pp. m90-2. Date of Electronic Publication: 2006 Feb 11. - Publication Year :
- 2006
-
Abstract
- The title compound, [Sn(C10H21N2)(C6H18NSi2)], contains the Sn(II) centre in a trigonal-pyramidal geometry. The basal plane is formed by three N atoms and the fourth apical position is occupied by a stereoactive lone pair. The Sn atom is displaced from the plane of the three N atoms by 1.1968 (12) A. The Sn-N bonds are highly polarized toward the N atoms, as confirmed by natural bonding orbital analysis.
Details
- Language :
- English
- ISSN :
- 0108-2701
- Volume :
- 62
- Issue :
- Pt 3
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section C, Crystal structure communications
- Publication Type :
- Academic Journal
- Accession number :
- 16518038
- Full Text :
- https://doi.org/10.1107/S0108270106001697