A high-nuclearity, beyond "fully reduced" polyoxo(alkoxo)vanadium(III/IV) cage.

Authors :: Tidmarsh IS
Laye RH
Brearley PR
Shanmugam M
Sañudo EC
Sorace L
Caneschi A
McInnes EJ
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2006 Jun 28 (24), pp. 2560-2. Date of Electronic Publication: 2006 May 18.
Publication Year :: 2006
Abstract: The solvothermal synthesis, crystal structure and preliminary magnetic studies are reported of the first high nuclearity V(III)-based polyoxo(alkoxo)vanadium cage, a V(III)16V(IV)2 complex.