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Highly diastereoselective oxidative addition of methyl iodide to a chiral square-planar complex.
- Source :
-
Inorganic chemistry [Inorg Chem] 2006 Aug 21; Vol. 45 (17), pp. 6559-61. - Publication Year :
- 2006
-
Abstract
- Oxidative addition of methyl iodide to the chiral square-planar complex IrI(CO)(duphos) shows a high level of diastereoselectivity. The basis for the diastereoselectivity of the reaction is best explained based on the crystal structure of IrI(CO)(duphos) in which methyl iodide approach across the two faces is differentiated by the chiral ligand.
Details
- Language :
- English
- ISSN :
- 0020-1669
- Volume :
- 45
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 16903699
- Full Text :
- https://doi.org/10.1021/ic052027v