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First mixed hydrazide/hydroxylamide metal aggregates.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2006 Oct 14 (38), pp. 3993-5. Date of Electronic Publication: 2006 Aug 10. - Publication Year :
- 2006
-
Abstract
- The first organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc, [Zn(MeZn)(4)(HNNMe(2))(2)(ONEt(2))(4)] and {Zn(EtZn)(4)[HNN(CH(2))(5)](2)(ONEt(2))(4)} were synthesized in one-pot synthesis protocols from dialkylzinc solutions, substituted hydrazines and N,N-diethylhydroxylamine; competing for the Zn atoms, the different binding properties of hydrazide and hydroxylamide ligands in these heteroleptic clusters are discussed.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 17003876
- Full Text :
- https://doi.org/10.1039/b608135e