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Three 1-thio-beta-D-glucopyranosides from the seeds of Afrostyrax lepidophyllus Mildbr.

Authors :
Ngane AN
Lavault M
Séraphin D
Landreau A
Richomme P
Source :
Carbohydrate research [Carbohydr Res] 2006 Dec 11; Vol. 341 (17), pp. 2799-802. Date of Electronic Publication: 2006 Oct 04.
Publication Year :
2006

Abstract

Three new 1-thioglycosides namely methylthiomethyl 1-thio-beta-D-glucopyranoside (Afrostyraxthioside A), methylsulfonylmethyl 1-thio-beta-D-glucopyranoside (Afrostyraxthioside B) and methylsulfonylmethylthiomethyl 1-thio-beta-D-glucopyranoside (Afrostyraxthioside C) were isolated from the seeds of Afrostyrax lepidophyllus Mildbr. Their structures were mainly elucidated by using one- and two-dimensional NMR and mass spectroscopies and also by an efficient one-step synthesis. Moreover, Afrostyraxthiosides A, B and C constitute a new subclass of 1-thioglycosides isolated from natural sources.

Details

Language :
English
ISSN :
0008-6215
Volume :
341
Issue :
17
Database :
MEDLINE
Journal :
Carbohydrate research
Publication Type :
Academic Journal
Accession number :
17054924
Full Text :
https://doi.org/10.1016/j.carres.2006.09.021