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[Photocatalytic degradation of hexafluorobenzene by tungstophosphoric acid].
- Source :
-
Huan jing ke xue= Huanjing kexue [Huan Jing Ke Xue] 2006 Aug; Vol. 27 (8), pp. 1501-7. - Publication Year :
- 2006
-
Abstract
- We verified that C6F6, a typical perfluorine compound, could be photocatalytic degraded by H3PW12O40. The defluorination of C6F6 was determined as a function of irradiation time, pH, initial concentration of H3PW12O40, and additives as well. The defluorination of C6F6 increased with the irradiation time. Acid condition, especially pH = 1.0 is preferred. 3 mL solution of 2.0 x 10(-4) mol/L C6F6 and 5.0 x 10(-6) mol/L H3PW12O40 was irradiated for 20 min and the defluorination of C6F6 was equal to 208.1%. O2, KMnO4 and K2S2O8 added in the solution were able to increase the defluorination of C6F6 via oxidating [PW12O40](4-). The defluorination of C6F6 would decline in the presence of alcohol and aromatic compounds.
Details
- Language :
- Chinese
- ISSN :
- 0250-3301
- Volume :
- 27
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- Huan jing ke xue= Huanjing kexue
- Publication Type :
- Academic Journal
- Accession number :
- 17111601