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Linkage isomerism in a face-centered cubic Cu6Cr8(CN)24 cluster with an S=15 ground state.

Authors :
Harris TD
Long JR
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2007 Apr 07 (13), pp. 1360-2. Date of Electronic Publication: 2007 Jan 19.
Publication Year :
2007

Abstract

Access to the new complex [TpCr(CN)3]- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN)24]4+, both exhibiting an S=15 ground state.

Details

Language :
English
ISSN :
1359-7345
Issue :
13
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
17377682
Full Text :
https://doi.org/10.1039/b615141h