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Ion-induced FRET on-off in fluorescent calix[4]arene.

Authors :
Lee MH
Quang DT
Jung HS
Yoon J
Lee CH
Kim JS
Source :
The Journal of organic chemistry [J Org Chem] 2007 May 25; Vol. 72 (11), pp. 4242-5. Date of Electronic Publication: 2007 May 01.
Publication Year :
2007

Abstract

A novel calix[4]arene bearing one 2,3-naphthocrown-6 and two coumarin amide units at the lower rim in partial-cone conformation was synthesized as a colorimetric and FRET-based fluorometric sensor for F(-) and Cs(+) ions. Intramolecular FRET from the naphthalene emission to the coumarin absorption affords high fluorescence selectivity toward F(-) and Cs(+) ions.

Details

Language :
English
ISSN :
0022-3263
Volume :
72
Issue :
11
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
17469875
Full Text :
https://doi.org/10.1021/jo070361y