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Simple preparation of diamondoid 1,3-dienes via oxetane ring opening.

Authors :
Fokin AA
Butova ED
Chernish LV
Fokina NA
Dahl JE
Carlson RM
Schreiner PR
Source :
Organic letters [Org Lett] 2007 Jun 21; Vol. 9 (13), pp. 2541-4. Date of Electronic Publication: 2007 May 25.
Publication Year :
2007

Abstract

The transformations of apical mono- and bisacetyl diamondoids to the respective oxetanes and subsequent acid-catalyzed ring opening/dehydration lead to diamondoidyl mono- and bis-1,3-dienes in high preparative yields.

Details

Language :
English
ISSN :
1523-7060
Volume :
9
Issue :
13
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
17523652
Full Text :
https://doi.org/10.1021/ol070920n