Metallophilic interactions in iodido(2,2':6',2''-terpyridine)platinum(II) diiodidoaurate(I).

Authors :: Angle CS
Woolard KJ
Kahn MI
Golen JA
Rheingold AL
Doerrer LH
Source :: Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2007 Jun; Vol. 63 (Pt 6), pp. m231-4. Date of Electronic Publication: 2007 May 11.
Publication Year :: 2007
Abstract: In the title compound, [PtI(C(15)H(11)N(3))][AuI(2)], the [PtI(terpy)](+) cations (terpy is 2,2':6',2''-terpyridine) stack in pairs about inversion centers through Pt...Pt interactions of 3.5279 (5) A. The [AuI(2)](-) anions also exhibit pairwise stacking, with Au...I distances of 3.7713 (5) A. The [PtI(terpy)](+) cations and [AuI(2)](-) anions aggregate forming infinite arrays of stacked ...([[PtI(terpy)](+)...[PtI(terpy)](+)]...[[AuI(2)](-)...[AuI(2)](-)])... units.

Language :: English
ISSN :: 0108-2701
Volume :: 63
Issue :: Pt 6
Database :: MEDLINE
Journal :: Acta crystallographica. Section C, Crystal structure communications
Publication Type :: Academic Journal
Accession number :: 17551175
Full Text :: https://doi.org/10.1107/S0108270107015843

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