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Above room temperature spin transition in a metallo-supramolecular coordination oligomer/polymer.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2007 Jul 07 (25), pp. 2636-8. Date of Electronic Publication: 2007 May 24. - Publication Year :
- 2007
-
Abstract
- By use of a metallo-supramolecular concept, a linear iron(ii) coordination chain [Fe(II)(L)](n)(BF(4))(2n) (L = 1,4-bis(1,2':6',1''-bispyrazolylpyridin-4'-yl)benzene) was rationally designed and synthesized. The molecular chain shows a reversible spin transition at 323 K with a ca. 10 K wide hysteresis loop.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 25
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 17579763
- Full Text :
- https://doi.org/10.1039/b702468a