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A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand.
- Source :
-
Inorganic chemistry [Inorg Chem] 2007 Oct 29; Vol. 46 (22), pp. 9021-3. Date of Electronic Publication: 2007 Sep 22. - Publication Year :
- 2007
-
Abstract
- A novel cobalt(II)-organic framework, [Co2(OH)(3,4-PBC)3]n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [CoII4(mu3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.
Details
- Language :
- English
- ISSN :
- 0020-1669
- Volume :
- 46
- Issue :
- 22
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 17887748
- Full Text :
- https://doi.org/10.1021/ic701003z