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Functionalized chiral ionic liquid catalyzed enantioselective desymmetrizations of prochiral ketones via asymmetric Michael addition reaction.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2007 Nov 23; Vol. 72 (24), pp. 9350-2. Date of Electronic Publication: 2007 Nov 02. - Publication Year :
- 2007
-
Abstract
- Functionalized chiral ionic liquids were found to be highly effective and reusable organocatalysts for asymmetric Michael additions of 4-substituted cyclohexanones. The desymmetrization reaction afforded the desired Michael adducts bearing three carbon stereocenters with up to 99% ee.
Details
- Language :
- English
- ISSN :
- 0022-3263
- Volume :
- 72
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 17975933
- Full Text :
- https://doi.org/10.1021/jo7020357