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Bis[N-(4-nitrophenyl)thiobenzamidato]mercury(II).

Authors :
Habibi MH
Tangestaninejad S
Fallah-Shojaie A
Mohammadpoor-Baltork I
Mokhtari R
Brooks NR
Clegg W
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2007 Nov; Vol. 63 (Pt 11), pp. m494-5. Date of Electronic Publication: 2007 Oct 13.
Publication Year :
2007

Abstract

The molecule of the title compound, [Hg(C(13)H(9)N(2)O(2)S)(2)], has approximate twofold rotation symmetry, with the Hg atom in an essentially linear two-coordinate HgS(2) environment supported by secondary pi interactions with the nitrophenyl rings of both ligands. The ligands are in the imine-thiolate rather than the amine-thione tautomeric form.

Details

Language :
English
ISSN :
1600-5759
Volume :
63
Issue :
Pt 11
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
17989461
Full Text :
https://doi.org/10.1107/S010827010704694X