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A new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium and the crystal structure of its palladium (II) complex.
- Source :
-
Molecules (Basel, Switzerland) [Molecules] 2005 Aug 31; Vol. 10 (8), pp. 912-21. Date of Electronic Publication: 2005 Aug 31. - Publication Year :
- 2005
-
Abstract
- A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO)2Cl2] in the extraction. X-ray crystal structure determination revealed PdCl2(ABSO)2 is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom.
Details
- Language :
- English
- ISSN :
- 1420-3049
- Volume :
- 10
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- Molecules (Basel, Switzerland)
- Publication Type :
- Academic Journal
- Accession number :
- 18007360
- Full Text :
- https://doi.org/10.3390/10080912