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Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Feb 28 (8), pp. 957-9. Date of Electronic Publication: 2008 Jan 22. - Publication Year :
- 2008
-
Abstract
- Trifunctional organocatalysts and mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3,700,000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.
- Subjects :
- Alcohols chemistry
Binding Sites
Biomimetic Materials chemical synthesis
Catalysis
Hydrogen Bonding
Molecular Conformation
Pyridines chemical synthesis
Time Factors
Alcohols chemical synthesis
Biomimetic Materials chemistry
Biomimetics
Esters chemistry
Pyridines chemistry
Thiourea chemistry
Vinyl Compounds chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18283348
- Full Text :
- https://doi.org/10.1039/b718763g