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Copper-catalyzed silylation of cyclopropenes using (trifluoromethyl)trimethylsilane.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Mar 07 (9), pp. 1124-6. Date of Electronic Publication: 2008 Jan 08. - Publication Year :
- 2008
-
Abstract
- A variety of cyclopropenes undergo direct silylation using (trifluoromethyl)trimethylsilane in the presence of a copper-bisphosphine catalyst; under these conditions, cyclopropenes that might otherwise undergo ring-opening are silylated efficiently.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18292911
- Full Text :
- https://doi.org/10.1039/b717568j