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Scaffolded amino acids as a close structural mimic of type-3 copper binding sites.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2007 Dec 14 (46), pp. 4895-7. - Publication Year :
- 2007
-
Abstract
- We report the use of triazacyclophane (TAC)-scaffolded amino acids as a structural mimic for 3-histidine metal-binding sites in metalloproteins, especially for the mimicry of type-3 copper binding sites as are present in hemocyanin, tyrosinase and catechol oxidase.
- Subjects :
- Binding Sites
Catechol Oxidase chemistry
Copper chemistry
Hemocyanins chemistry
Histidine chemistry
Indicators and Reagents
Molecular Conformation
Molecular Mimicry
Monophenol Monooxygenase chemistry
Oxygen chemistry
Spectrophotometry, Infrared
Spectrophotometry, Ultraviolet
Spectrum Analysis, Raman
Vibration
Amino Acids chemistry
Copper metabolism
Metalloproteins chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 46
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18361361
- Full Text :
- https://doi.org/10.1039/b709400k