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Atom efficient cyclotrimerization of dimethylcyanamide catalyzed by aluminium amide: a combined experimental and theoretical investigation.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Aug 21 (31), pp. 3645-7. Date of Electronic Publication: 2008 Jun 20. - Publication Year :
- 2008
-
Abstract
- A novel method for the cyclotrimerization of dimethylcyanamide to form hexamethylmelamine has been developed using an aluminium amide catalyst; detailed DFT modelling of the catalytic cycle supports a triple insertion, nucleophilic ring closure, deinsertion mechanism.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Issue :
- 31
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 18665286
- Full Text :
- https://doi.org/10.1039/b803732a