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Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2008 Oct 17; Vol. 73 (20), pp. 7985-9. Date of Electronic Publication: 2008 Sep 18. - Publication Year :
- 2008
-
Abstract
- An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 73
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 18798672
- Full Text :
- https://doi.org/10.1021/jo801236c