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Extraordinary circularly polarized luminescence activity exhibited by cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2008 Oct 22; Vol. 130 (42), pp. 13814-5. Date of Electronic Publication: 2008 Sep 25. - Publication Year :
- 2008
-
Abstract
- The largest CPL activity ever measured was observed for cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions substantiating the stereospecific formation of chiral Delta-SAPR-(C4) configuration with the aid of Cs+...FC (fluorocarbon) interactions more clearly than the exciton CD spectra.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 130
- Issue :
- 42
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 18816117
- Full Text :
- https://doi.org/10.1021/ja805681w