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Extraordinary circularly polarized luminescence activity exhibited by cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions.

Authors :
Lunkley JL
Shirotani D
Yamanari K
Kaizaki S
Muller G
Source :
Journal of the American Chemical Society [J Am Chem Soc] 2008 Oct 22; Vol. 130 (42), pp. 13814-5. Date of Electronic Publication: 2008 Sep 25.
Publication Year :
2008

Abstract

The largest CPL activity ever measured was observed for cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions substantiating the stereospecific formation of chiral Delta-SAPR-(C4) configuration with the aid of Cs+...FC (fluorocarbon) interactions more clearly than the exciton CD spectra.

Details

Language :
English
ISSN :
1520-5126
Volume :
130
Issue :
42
Database :
MEDLINE
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
18816117
Full Text :
https://doi.org/10.1021/ja805681w