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Snowman-like silver alkynyl cluster consolidated by templating chloride and peripheral trifluoroacetates.

Authors :
Bian SD
Wang QM
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Nov 21 (43), pp. 5586-8. Date of Electronic Publication: 2008 Sep 25.
Publication Year :
2008

Abstract

A novel nonadecanuclear silver double cage was isolated, in which a square antiprism and a pentacapped pentagonal prism templated by a chloride ion share a tetragonal face to form a snowman-like cluster that is held together by bridging alkynyl groups and trifluoroacetates.

Details

Language :
English
ISSN :
1359-7345
Issue :
43
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
18997960
Full Text :
https://doi.org/10.1039/b812451e