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Reaction of benzyne with salicylaldehydes: general synthesis of xanthenes, xanthones, and xanthols.

Authors :
Okuma K
Nojima A
Matsunaga N
Shioji K
Source :
Organic letters [Org Lett] 2009 Jan 01; Vol. 11 (1), pp. 169-71.
Publication Year :
2009

Abstract

The reaction of salicylaldehydes with benzyne prepared from o-trimethylsilyphenyl triflate and CsF gave xanthenes and xanthones. When the reaction was carried out under basic conditions, 9-hydroxyxanthenes (xanthols) were obtained in good yields.

Details

Language :
English
ISSN :
1523-7052
Volume :
11
Issue :
1
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
19053733
Full Text :
https://doi.org/10.1021/ol802597x