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Synthesis of spiroheterocycles by palladium-catalyzed domino cycloisomerization/cross-coupling of alpha-allenols and Baylis-Hillman acetates.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2009; Vol. 15 (14), pp. 3344-6. - Publication Year :
- 2009
-
Abstract
- First insights into the reaction between a Baylis-Hillman adduct and an allene moiety have been obtained from the novel domino heterocyclization/cross-coupling reaction of alpha-allenols and Baylis-Hillman acetates, which furnishes [(2,5-dihydrofuran-3-yl)methyl]acrylate derivatives in moderate to good yields.
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 15
- Issue :
- 14
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 19229919
- Full Text :
- https://doi.org/10.1002/chem.200900096