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Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2009 Apr 08; Vol. 131 (13), pp. 4590-1. - Publication Year :
- 2009
-
Abstract
- X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz)(2)(S(2)O(8)) consists of 2D square nets of Ag(2+) ions resulting from the corner-sharing of axially elongated AgN(4)O(2) octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, mu(+)SR measurements indicate that Ag(pyz)(2)(S(2)O(8)) undergoes 3D magnetic ordering below 7.8(3) K.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 131
- Issue :
- 13
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 19334770
- Full Text :
- https://doi.org/10.1021/ja9005223