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Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo[quadruple bond]W...Cr chain.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2009 Aug 07 (29), pp. 4357-9. Date of Electronic Publication: 2009 May 19. - Publication Year :
- 2009
-
Abstract
- Addition of CrCl(2) to the dinuclear synthon MoW(dpa)(4) yields a regioselectively formed heterotrimetallic Mo[quadruple bond]W...Cr chain; computational studies suggest that the polarization of the Mo[quadruple bond]W quadruple bond partially accounts for this unexpected selectivity.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Issue :
- 29
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 19597591
- Full Text :
- https://doi.org/10.1039/b907402c