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Daphhimalenine A, a new alkaloid with an unprecedented skeleton, from Daphniphyllum himalense.
- Source :
-
Organic letters [Org Lett] 2009 Dec 03; Vol. 11 (23), pp. 5414-7. - Publication Year :
- 2009
-
Abstract
- Daphhimalenine A (1), a novel alkaloid with a rearrangement C-21 skeleton, containing a unique 1-azabicyclo[5.2.1]decane ring system, was isolated from the leaves of Daphniphyllum himalense, along with biogenetically related alkaloids daphhimalenine B (2) and daphnezomine T. Their structures were established on the basis of spectroscopic data, and the absolute configuration of 1 was assigned by computational methods. A plausible biosynthetic pathway of 1 was also proposed.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 11
- Issue :
- 23
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 19904981
- Full Text :
- https://doi.org/10.1021/ol902262g