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Trapping of atomic hydrogens in cage-shaped silsesquioxanes by electric discharge.

Authors :
Harima Y
Komaguchi K
Oka K
Maruoka T
Imae I
Ooyama Y
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Mar 28; Vol. 46 (12), pp. 2076-8. Date of Electronic Publication: 2010 Feb 16.
Publication Year :
2010

Abstract

A simple and safe technique which is based on glow discharge is demonstrated for stable encapsulation of H atoms in cage-shaped silsesquioxanes at room temperature, leading to the encapsulation yield of ca. 10(-4) H atoms per molecule for 10-minute discharging, much faster than the conventional gamma-ray irradiation technique.

Details

Language :
English
ISSN :
1364-548X
Volume :
46
Issue :
12
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
20221497
Full Text :
https://doi.org/10.1039/b917165g