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Tris(1,10-phenanthroline-kappa2N,N')cadmium(II) bis(perchlorate) 3.5-hydrate: a water chain stabilized by perchlorate anions.

Authors :
Sun YH
Du ZY
Zhang SY
He YF
Zhou ZG
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2010 Apr; Vol. 66 (Pt 4), pp. m104-6. Date of Electronic Publication: 2010 Mar 06.
Publication Year :
2010

Abstract

The title compound, [Cd(C(12)H(8)N(2))(3)](ClO(4))(2).3.5H(2)O, contains a cross-shaped one-dimensional channel along the c axis which encapsulates an ordered water chain. This water chain features a centrosymmetric cyclic water hexamer unit with a chair-like conformation. Neighbouring hexamers are linked by bridging water molecules. The host perchlorate anions recognize and stabilize the guest water chain via three kinds of hydrogen-bond patterns, leading to the formation of a complex one-dimensional {[(H(2)O)(7)(ClO(4))(4)](4-)}(n) anionic chain. One perchlorate acts as a single hydrogen-bond acceptor dangling on the chain, the second perchlorate on the chain serves as a double hydrogen-bond acceptor for only one water molecule to form an R(2)(2)(6) ring, where both entities lie on a twofold axis, while the third perchlorate, which also lies on a twofold axis, accepts two hydrogen bonds from two equivalent water molecules and is involved in the construction of an R(6)(5)(14) ring.

Details

Language :
English
ISSN :
1600-5759
Volume :
66
Issue :
Pt 4
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
20354289
Full Text :
https://doi.org/10.1107/S0108270110004567