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Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water.

Authors :
Besson C
Huang Z
Geletii YV
Lense S
Hardcastle KI
Musaev DG
Lian T
Proust A
Hill CL
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Apr 28; Vol. 46 (16), pp. 2784-6. Date of Electronic Publication: 2010 Feb 25.
Publication Year :
2010

Abstract

The tetraruthenium-substituted polyoxometalate Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)] was synthesized and structurally, spectroscopically and electrochemically characterized; it was shown to be a catalyst for visible-light-induced water oxidation.

Details

Language :
English
ISSN :
1364-548X
Volume :
46
Issue :
16
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
20369182
Full Text :
https://doi.org/10.1039/b926064a