Back to Search Start Over

A new family of oxime-based hexanuclear manganese(III) single molecule magnets with high anisotropy energy barriers.

Authors :
Tomsa AR
Martínez-Lillo J
Li Y
Chamoreau LM
Boubekeur K
Farias F
Novak MA
Cremades E
Ruiz E
Proust A
Verdaguer M
Gouzerh P
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Jul 28; Vol. 46 (28), pp. 5106-8. Date of Electronic Publication: 2010 Jun 07.
Publication Year :
2010

Abstract

A magneto-structural study of two salicylamidoxime-based {Mn(6)} single-molecule magnets revealed that their anisotropy energy barriers, which can reach the current record for d-transition metal complexes, are strongly dependent upon the precise arrangement of ligands and the solvation state.

Details

Language :
English
ISSN :
1364-548X
Volume :
46
Issue :
28
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
20532259
Full Text :
https://doi.org/10.1039/c0cc00485e