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Tetra-aqua-bis(2-oxo-1,2-dihydro-quinoline-4-carboxyl-ato-κO)nickel(II).

Authors :
Yuan G
Qin JS
Su ZM
Shao KZ
Fu YM
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2008 Jan 23; Vol. 64 (Pt 2), pp. m389-90. Date of Electronic Publication: 2008 Jan 23.
Publication Year :
2008

Abstract

In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octa-hedral geometry by two O atoms from two 2-oxo-1,2-dihydro-quinoline-4-carboxyl-ate ligands and four water mol-ecules, all of which act as monodentate ligands. The crystal structure features an extensive network of inter-molecular hydrogen-bonding inter-actions (O-H⋯O and N-H⋯O) and offset face-to-face π-π stacking inter-actions [centroid-centroid distances = 3.525 (3) and 3.281 (5) Å].

Details

Language :
English
ISSN :
1600-5368
Volume :
64
Issue :
Pt 2
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21201341
Full Text :
https://doi.org/10.1107/S1600536807065671