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[3-Hydr-oxy-N'-(2-oxidobenzyl-idene)-2-naphthohydrazidato-κO,N,O']tris-(pyridine-κN)nickel(II) pyridine tris-olvate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2008 Jan 30; Vol. 64 (Pt 2), pp. m438. Date of Electronic Publication: 2008 Jan 30. - Publication Year :
- 2008
-
Abstract
- The asymmetric unit of the crystal structure of the title complex, [Ni(C(18)H(12)N(2)O(3))(C(5)H(5)N)(3)]·3C(5)H(5)N, contains two independent Ni(II) complex mol-ecules and six uncoordinated pyridine mol-ecules. Each Ni(II) atom is coordinated by two O and four N atoms, from three pyridine and a chelating 3-hydr-oxy-N'-(2-oxidobenzyl-idene)-2-naphthohydrazide dianionic ligand, with a distorted octa-hedral geometry. Intra-molecular O-H⋯N hydrogen bonding exists in both complex mol-ecules but no inter-molecular hydrogen bonding is observed in the crystal structure.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 64
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21201379
- Full Text :
- https://doi.org/10.1107/S1600536808002900