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Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Mar 07; Vol. 47 (9), pp. 2532-4. Date of Electronic Publication: 2011 Jan 12. - Publication Year :
- 2011
-
Abstract
- The β-sheet structure associated with chlorinated aromatics (d(Cl···Cl)≈ 4.0 Å) has been implemented to drive formation of π-stacked structures of dithiadiazolyl radicals. Both title compounds exhibit an increase in paramagnetism above 150 K but solid-state EPR studies indicate that the origin of the paramagnetism in these two systems is different.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 47
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 21229137
- Full Text :
- https://doi.org/10.1039/c0cc04296j