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2,2,5,7,8-Penta-methyl-chroman-6-yl 2,3,4,6-tetra-O-acetyl-α-d-glucopyran-oside from synchrotron data.

Authors :
Brzezinski K
Wałejko P
Baj A
Witkowski S
Dauter Z
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2011 Feb 26; Vol. 67 (Pt 3), pp. o718. Date of Electronic Publication: 2011 Feb 26.
Publication Year :
2011

Abstract

The crystal structure of the title compound, C(28)H(38)O(11), solved and refined against synchrotron diffraction data, contains two formula units in the asymmetric unit. In both mol-ecules, the dihydro-pyran ring along with its methyl substituents is disordered and adopts two alternative half-chair conformations. The occupancy of the major conformers of the two mol-ecules refined to 0.858 (5) and 0.523 (5).

Details

Language :
English
ISSN :
1600-5368
Volume :
67
Issue :
Pt 3
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21522460
Full Text :
https://doi.org/10.1107/S160053681100626X