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Theoretical modeling on the kinetics of the arsenate-ester hydrolysis: implications to the stability of As-DNA.
- Source :
-
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2011 Jun 21; Vol. 13 (23), pp. 10869-71. Date of Electronic Publication: 2011 May 11. - Publication Year :
- 2011
-
Abstract
- Quantum chemical calculations reveal that neither steric hindrance nor less polar solvent medium is able to reduce the otherwise high hydrolysis rate of arsenate-esters. These results question the stability of As-DNA not only in aqueous but also in non-aqueous environments.
Details
- Language :
- English
- ISSN :
- 1463-9084
- Volume :
- 13
- Issue :
- 23
- Database :
- MEDLINE
- Journal :
- Physical chemistry chemical physics : PCCP
- Publication Type :
- Academic Journal
- Accession number :
- 21562664
- Full Text :
- https://doi.org/10.1039/c1cp20423h