Structural interconversion between a chain polymer and a two-dimensional network accompanied by tunable magnetic properties.

Authors :: Chen C
Sun JK
Li W
Chen CN
Zhang J
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Jun 21; Vol. 47 (23), pp. 6683-5. Date of Electronic Publication: 2011 May 12.
Publication Year :: 2011
Abstract: The reaction of 2-hydroxypyrimidine-4,6-dicarboxylic acid (H(3)hpdc) with CuCl(2) under different temperatures gives a chain-like compound [Cu(2)(hpdc)(OH)(H(2)O)(4)]·H(2)O and a layer-like compound [Cu(2)(hpdc)(OH)(H(2)O)], which exhibit structural interconversion and tunable magnetic properties upon dehydration and hydration.<br /> (This journal is © The Royal Society of Chemistry 2011)

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