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(μ-3-Acetyl-5-carboxyl-ato-4-methyl-pyrazolido-1:2κN,O:N,O)-μ-chlorido-tetra-pyridine-1κN,2κN-chlorido-1κCl-dicopper(II) propan-2-ol solvate.

Authors :
Malinkin S
Penkova L
Pavlenko VA
Haukka M
Fritsky IO
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Sep 26; Vol. 65 (Pt 10), pp. m1247-8. Date of Electronic Publication: 2009 Sep 26.
Publication Year :
2009

Abstract

The title compound, [Cu(2)(C(7)H(6)N(2)O(3))Cl(2)(C(5)H(5)N)(4)]·C(3)H(8)O, is a binuclear pyrazolate complex, in which the two Cu(II) atoms have different coordination numbers and are connected by a bridging Cl atom. One Cu(II) atom has a distorted square-pyramidal coordination environment formed by two pyridine N atoms, one bridging Cl atom and an N,O-chelating pyrazolate ligand. The other Cu(II) atom adopts an octa-hedral geometry defined by two pyridine N atoms at the axial positions, two Cl atoms and the coordinated pyrazolate ligand in the equatorial plane. An O-H⋯O hydrogen bond connects the complex mol-ecules and propan-2-ol solvent mol-ecules into pairs. These pairs form columns along the a axis.

Details

Language :
English
ISSN :
1600-5368
Volume :
65
Issue :
Pt 10
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21577764
Full Text :
https://doi.org/10.1107/S1600536809038276