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Bis[(E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolato-κN,O]copper(II).

Authors :
Gong SS
Dong WK
Tong JF
Li L
Wu JC
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Oct 31; Vol. 65 (Pt 11), pp. m1471. Date of Electronic Publication: 2009 Oct 31.
Publication Year :
2009

Abstract

The title compound, [Cu(C(9)H(9)BrNO(2))(2)], is a centrosymmetric mononuclear copper(II) complex. The Cu atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two oxime N atoms from two symmetry-related N,O-bidentate (E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolate oxime-type ligands. An inter-esting feature of the crystal structure is the centrosymmetric inter-molecular Cu⋯O inter-action [3.382 (1) Å], which establishes an infinite chain structure along the b axis.

Details

Language :
English
ISSN :
1600-5368
Volume :
65
Issue :
Pt 11
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21578195
Full Text :
https://doi.org/10.1107/S160053680904433X