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(E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl-iminomethyl}-6-methoxyphenol mono-hydrate.

Authors :
Tong JF
Gao SX
Dong WK
Li HF
Wu JC
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Oct 17; Vol. 65 (Pt 11), pp. o2764. Date of Electronic Publication: 2009 Oct 17.
Publication Year :
2009

Abstract

In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intra-molecular O-H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the mol-ecules are connected into a three-dimensional network via O-H⋯O and O-H⋯N inter-molecular hydrogen bonds, forming a centrosymmetric ring along the b axis with graph-set motif R(4) (4)(10). In addition, the short distances between the centroids of six-membered rings [3.555 (1) Å], indicate the existence of π-π stacking inter-actions, which may stabilize the crystal structure.

Details

Language :
English
ISSN :
1600-5368
Volume :
65
Issue :
Pt 11
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21578358
Full Text :
https://doi.org/10.1107/S1600536809042032