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Tetra-kis(μ-6-hydr-oxy-1-naphthoato)bis-[(6-hydr-oxy-1-naphthoato)(1,10-phenanthroline)europium(III)] dihydrate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Nov 14; Vol. 65 (Pt 12), pp. m1572-3. Date of Electronic Publication: 2009 Nov 14. - Publication Year :
- 2009
-
Abstract
- The title complex, [Eu(2)(C(11)H(7)O(3))(6)(C(12)H(8)N(2))(2)]·2H(2)O, has a centrosymmetric binuclear cage structure in which the two Eu(III) ions are both nine-coordinated and bridged by 6-hy-droxy-1-naphthoate (L) ligands, with an Eu⋯ Eu separation of 4.1594 (4) Å. The remaining coordination sites are occupied by two N atoms from one 1,10-phenanthroline (phen) and two O atoms from an L ligand. The six 6-hydr-oxy-1-naphthoate groups coordinate each Eu(III) atom in three different ways, namely μ(2)-η(1):η(1)-bridging, μ(1)-η(1):η(1)-chelating, and μ(2)-η(1):η(2)-chelating/bridging modes. Adjacent discrete dinuclear units are linked into a two-dimensional sheet parallel to (011) by inter-molecular O-H⋯O hydrogen-bonding inter-actions. The sheets are cross-linked by water mol-ecules, forming a three-dimensional network. In addition, π-π stacking inter-actions, with a centroid-centroid separation of 3.547 (2) Å are observed.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 65
- Issue :
- Pt 12
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21578606
- Full Text :
- https://doi.org/10.1107/S1600536809046091