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Tetra-μ-acetato-κO:O';κO,O':O';κO:O,O'-bis-[(acetato-κO,O')(1,10-phenanthroline-κN,N')europium(III)].

Authors :
Liu WJ
Li ZY
Wei ZQ
Yue ST
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 May 08; Vol. 66 (Pt 6), pp. m606. Date of Electronic Publication: 2010 May 08.
Publication Year :
2010

Abstract

In the title centrosymmetric dinuclear Eu(III) complex, [Eu(2)(CH(3)COO)(6)(C(12)H(8)N(2))(2)], each Eu(III) cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two Eu(III) cations to form the dinuclear complex, with an Eu⋯Eu distance of 3.9409 (8) Å. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal structure.

Details

Language :
English
ISSN :
1600-5368
Volume :
66
Issue :
Pt 6
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21579268
Full Text :
https://doi.org/10.1107/S1600536810015680