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(6-Acetyl-1,3,7-trimethyl-lumazine-κO,N,O)bis-(triphenyl-phosphine-κP)copper(I) hexa-fluorido-phosphate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Jan 13; Vol. 66 (Pt 2), pp. m145-6. Date of Electronic Publication: 2010 Jan 13. - Publication Year :
- 2010
-
Abstract
- The title compound, [Cu(C(11)H(12)N(4)O(3))(C(18)H(15)P)(2)]PF(6), is the third example reported in the literature of a five-coordinated Cu(I)P(2)NO(2) system. The metal is coordinated to both PPh(3) mol-ecules through the P atoms and to the pyrazine ring of the lumazine mol-ecule through an N atom in a trigonal-planar arrangement; two additional coordinated O atoms, at Cu-O distances longer than 2.46 Å, complete the coordination. The coordination environment can be described as an inter-mediate square-pyramidal/trigonal-bipyramidal (SP/TBP) polyhedron.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 66
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21579625
- Full Text :
- https://doi.org/10.1107/S1600536810000735