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Bis[1,3-bis-(benzimidazol-2-yl)-2-oxa-propane]cobalt(II) dipicrate acetonitrile tris-olvate.

Authors :
Wu H
Yun R
Huang X
Sun Q
Qi B
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Jul 01; Vol. 65 (Pt 8), pp. m851. Date of Electronic Publication: 2009 Jul 01.
Publication Year :
2009

Abstract

In the title compound, [Co(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·3CH(3)CN, the Co(II) ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra-hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds. One of the acetonitrile solvent mol-ecules also lies on a twofold rotation axis.

Details

Language :
English
ISSN :
1600-5368
Volume :
65
Issue :
Pt 8
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21583320
Full Text :
https://doi.org/10.1107/S1600536809024234