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catena-Poly[[[tetra-aqua-manganese(II)]-μ-4,4'-bipyridine] bis-(3-hydroxy-cinnamate) dihydrate].
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Jul 22; Vol. 65 (Pt 8), pp. m979. Date of Electronic Publication: 2009 Jul 22. - Publication Year :
- 2009
-
Abstract
- The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydro-thermal reaction of manganese chloride with mixed 3-hydroxy-lcinnamic acid (H(2)L) and 4,4'-bipyridine (4,4'-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4'-bipy ligands, surrounded by HL(-) anions and uncoordinated water mol-ecules. Extensive O-H⋯O hydrogen-bonding and weak π-π inter-actions [centroid-centroid distance = 3.7572 (3) Å] between the constituents lead to the formation of a three-dimensional supra-molecular network.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 65
- Issue :
- Pt 8
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21583422
- Full Text :
- https://doi.org/10.1107/S1600536809028360