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catena-Poly[[[tetra-aqua-manganese(II)]-μ-4,4'-bipyridine] bis-(3-hydroxy-cinnamate) dihydrate].

Authors :
Tang ZW
Fu JD
Jiang LP
Wen YH
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Jul 22; Vol. 65 (Pt 8), pp. m979. Date of Electronic Publication: 2009 Jul 22.
Publication Year :
2009

Abstract

The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydro-thermal reaction of manganese chloride with mixed 3-hydroxy-lcinnamic acid (H(2)L) and 4,4'-bipyridine (4,4'-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4'-bipy ligands, surrounded by HL(-) anions and uncoordinated water mol-ecules. Extensive O-H⋯O hydrogen-bonding and weak π-π inter-actions [centroid-centroid distance = 3.7572  (3) Å] between the constituents lead to the formation of a three-dimensional supra-molecular network.

Details

Language :
English
ISSN :
1600-5368
Volume :
65
Issue :
Pt 8
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21583422
Full Text :
https://doi.org/10.1107/S1600536809028360