Back to Search Start Over

Enantioselective conjugate allylation of cyclic enones.

Authors :
Taber DF
Gerstenhaber DA
Berry JF
Source :
The Journal of organic chemistry [J Org Chem] 2011 Sep 16; Vol. 76 (18), pp. 7614-7. Date of Electronic Publication: 2011 Aug 23.
Publication Year :
2011

Abstract

Enantioselective organocatalytic 1,2-allylation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture of diastereomers. This appears to be a general method for the net enantioselective conjugate allylation of cyclic enones.<br /> (© 2011 American Chemical Society)

Details

Language :
English
ISSN :
1520-6904
Volume :
76
Issue :
18
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
21830779
Full Text :
https://doi.org/10.1021/jo2013753