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An oxidative coupling route to macrocyclic thiophenes and its application in the synthesis of a donor/acceptor hybrid molecule.

Authors :
Maier SK
Jester SS
Müller U
Müller WM
Höger S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Oct 21; Vol. 47 (39), pp. 11023-5. Date of Electronic Publication: 2011 Sep 12.
Publication Year :
2011

Abstract

A route towards phenylene-bithiophene macrocycles via oxidative thiophene coupling under pseudo-high dilution conditions is reported. This method is applied to the synthesis of a shape-persistent thiophene macrocycle with extraannularly attached perylenebisimide moieties that forms supramolecular aggregates at the solid/liquid interface.

Details

Language :
English
ISSN :
1364-548X
Volume :
47
Issue :
39
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
21909541
Full Text :
https://doi.org/10.1039/c1cc14664e