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Collisional relaxation of MnH (X7Σ+) in a magnetic field: effect of the nuclear spin of Mn.

Authors :
Stoecklin T
Halvick P
Source :
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2011 Nov 14; Vol. 13 (42), pp. 19142-7. Date of Electronic Publication: 2011 Sep 22.
Publication Year :
2011

Abstract

In the present study we investigate the role played by the hyperfine structure of manganese in the cooling and magnetic trapping of MnH((7)Σ(+)). The effect of the hyperfine structure of Mn on the relaxation of the magnetically trappable maximally stretched low-field seeking state of MnH((7)Σ(+)) in collisions with (3)He is deduced from comparison between the results of the present approach and our previous nuclear spin free calculations. We show that our previous results are unchanged at the temperature of the buffer gas cooling experiment but find a new resonance at very low collision energy. The role played by the different contributions to the hyperfine diatomic Hamiltonian considered in this work as well as the effect of an applied magnetic field on this resonance are also analyzed.

Details

Language :
English
ISSN :
1463-9084
Volume :
13
Issue :
42
Database :
MEDLINE
Journal :
Physical chemistry chemical physics : PCCP
Publication Type :
Academic Journal
Accession number :
21947359
Full Text :
https://doi.org/10.1039/c1cp21466g